The Chemistry Behind Nitrilotris([1,1'-biphenyl]-3,5-dicarboxylic acid) Linkers in Framework Materials
The construction of advanced porous materials like Covalent Organic Frameworks (COFs) and Metal-Organic Frameworks (MOFs) relies heavily on the careful selection and synthesis of organic linker molecules. Among these, 4',4''',4'''''-nitrilotris([1,1'-biphenyl]-3,5-dicarboxylic acid), identified by its CAS number 1347748-59-7, plays a significant role. This compound is a prime example of a complex organic building block designed for precise framework assembly.
At its core, nitrilotris([1,1'-biphenyl]-3,5-dicarboxylic acid) features a central triphenylamine moiety. This nitrogen atom, bonded to three phenyl rings, provides a robust and geometrically defined core. Each of these phenyl rings is further substituted with carboxylic acid groups at the 3 and 5 positions, making it a multi-carboxylic acid derivative. This specific arrangement of functional groups is what makes it an excellent linker. The carboxylic acid groups can readily coordinate with metal ions in MOFs or participate in covalent bond formation within COFs, creating extended, highly ordered structures.
The high purity of this COF monomer (typically >97%) is essential for achieving well-defined crystalline frameworks. Impurities can disrupt the self-assembly process, leading to defects or amorphous materials, thereby compromising the desired properties. The triphenylamine core linker for MOFs offers excellent thermal and chemical stability, contributing to the overall robustness of the resulting frameworks.
Understanding the chemistry of nitrilotris([1,1'-biphenyl]-3,5-dicarboxylic acid) is key for researchers and manufacturers. When considering its purchase, one must look for suppliers who can guarantee consistent quality and purity. The versatility of this molecule means that it can be tailored for various applications, from gas capture and separation to sensing and drug delivery, by strategically choosing the co-reactants and synthesis conditions. Its importance in advancing materials science highlights the power of designing intricate organic molecules for specific, high-performance applications.
Perspectives & Insights
Chem Catalyst Pro
“The carboxylic acid groups can readily coordinate with metal ions in MOFs or participate in covalent bond formation within COFs, creating extended, highly ordered structures.”
Agile Thinker 7
“The high purity of this COF monomer (typically >97%) is essential for achieving well-defined crystalline frameworks.”
Logic Spark 24
“Impurities can disrupt the self-assembly process, leading to defects or amorphous materials, thereby compromising the desired properties.”