For chemists, material scientists, and process engineers, a deep understanding of chemical properties and synthesis pathways is fundamental to innovation and efficient production. Himic Anhydride (CAS 826-62-0) is a compound of significant interest due to its versatile reactivity and utility as a chemical intermediate. This article explores its key chemical properties, typical characteristics, and general synthesis considerations, providing valuable insights for those looking to buy or utilize this important substance.

Chemical Identity and Core Properties

Himic Anhydride, also known by its IUPAC name 3,6-Endomethylene-1,2,3,6-tetrahydrophthalic anhydride, is an organic compound with the molecular formula C9H8O3 and a molecular weight of 164.16 g/mol. Its structure features a bicyclic ring system derived from norbornene, incorporating an anhydride functional group. This anhydride moiety is responsible for much of its reactivity.

Key properties commonly reported for Himic Anhydride include:

  • Appearance: Typically a White Solid. This solid form facilitates handling, storage, and precise dosing in chemical processes.
  • Purity: Industrial grades generally offer a minimum assay of 98.0%, ensuring consistent reactivity and performance in downstream applications.
  • Melting Point: Approximately 162.0°C. This relatively high melting point indicates a stable solid state at room temperature and is a critical parameter for quality control.
  • Solubility: While specific comprehensive solubility data can vary, anhydrides are generally soluble in many organic solvents like ethers and acetone, but reactive with water.

The anhydride functional group makes Himic Anhydride susceptible to nucleophilic attack, readily hydrolyzing in the presence of water to form the corresponding diacid. This reactivity is precisely what makes it valuable as a crosslinking agent and intermediate.

Synthesis Considerations

The synthesis of Himic Anhydride typically involves a Diels-Alder reaction. A common route involves the reaction between maleic anhydride and cyclopentadiene. The initial adduct formed undergoes subsequent reactions to yield the desired endo-isomer, which is the predominant form of Himic Anhydride.

The basic reaction can be represented as:

Maleic Anhydride + Cyclopentadiene → 3,6-Endomethylene-1,2,3,6-tetrahydrophthalic Anhydride (Himic Anhydride)

The specific conditions of the reaction, including temperature, pressure, catalyst (if any), and solvent, are optimized by manufacturers to maximize yield and purity, often favoring the endo isomer. Post-synthesis purification steps are crucial to achieve the high assay (≥98%) demanded by the market.

Procurement and Quality Assurance

For researchers and industrial users, sourcing Himic Anhydride from a reliable supplier is essential. When you choose to buy from a reputable manufacturer, you can expect detailed specifications, Certificates of Analysis (COA) that confirm purity and key properties, and guidance on safe handling and storage. Manufacturers often offer it in standard packaging like 25kg drums or bags, with options for sea or air freight.

Conclusion: A Foundation for Chemical Innovation

Himic Anhydride (CAS 826-62-0) is a chemically robust and versatile intermediate. Its well-defined properties and synthesis pathway make it a reliable component for numerous industrial processes. By understanding its chemistry, potential buyers can make informed decisions when sourcing this compound, ensuring optimal performance in applications ranging from advanced polymers to specialty chemicals.