Ammonium formate (CAS 540-69-2) is a fundamental chemical compound with a well-defined set of properties that make it suitable for a wide array of applications. Understanding these characteristics, along with its synthesis and safe handling procedures, is crucial for its effective use in both research and industrial settings. This article provides a detailed look into the properties, synthesis, and safety considerations associated with ammonium formate.

Chemical Properties and Stability: Ammonium formate is the ammonium salt of formic acid, with the chemical formula CH5NO2. It is highly soluble in water and other polar solvents, dissociating into ammonium and formate ions in aqueous solutions. While stable under normal ambient conditions, it decomposes at elevated temperatures, typically above its melting point of 116-117°C, releasing ammonia (NH3) and carbon dioxide (CO2). This decomposition characteristic is important to consider during storage and processing.

Physical Properties: As a white crystalline solid, ammonium formate has a slight ammoniac odor. Its molecular weight is 63.06 g/mol, and its density is approximately 1.26-1.36 g/cm³. The solid form is hygroscopic, meaning it readily absorbs moisture from the air, which necessitates proper storage in sealed containers.

Synthesis: The most common method for synthesizing ammonium formate involves the direct neutralization reaction between formic acid (HCOOH) and ammonia (NH3). The reaction is straightforward and can be carried out under mild conditions, making it an economically viable process for large-scale production. Other methods, such as the reaction of ammonium carbonate with formic acid, exist but are less frequently employed industrially.

Safety and Handling: While generally considered to have low toxicity, proper safety precautions should always be taken when handling ammonium formate. Due to its hygroscopic nature and potential to release ammonia upon decomposition, adequate ventilation is recommended, especially in enclosed spaces. It should be stored in a cool, dry place, away from incompatible materials such as strong oxidizing agents and strong acids. Personal protective equipment (PPE), including gloves and eye protection, is advised to prevent skin and eye irritation. Responsible disposal practices are also important to minimize environmental impact.

By understanding these properties, synthesis routes, and safety guidelines, users can effectively and safely incorporate ammonium formate into their chemical processes. NINGBO INNO PHARMCHEM CO.,LTD. offers high-purity ammonium formate, ensuring that our clients receive a product that meets stringent quality requirements for all their applications.