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Advanced Halogen-Free Aluminum Diethyl Phosphinate for Polymer Fire Safety

Fire safety stands as a paramount concern in the development and application of modern materials, particularly within electrical, electronic, and construction sectors. As industries increasingly move towards sustainable and environmentally responsible solutions, the demand for high-performance, halogen-free flame retardants has grown significantly. Among these advanced materials, Aluminum Diethyl Phosphinate (ADP), identified by CAS number 225789-38-8, emerges as a leading solution, offering exceptional fire safety properties without the environmental drawbacks associated with traditional halogenated compounds.


ADP functions through a sophisticated dual-phase mechanism to effectively suppress combustion. In the condensed phase, upon exposure to heat, ADP promotes the formation of a stable char layer on the polymer's surface. This carbonaceous barrier acts as an insulating shield, limiting the transfer of heat to the underlying material and impeding the release of combustible gases, thereby slowing down the burning process. Simultaneously, in the gas phase, ADP undergoes thermal decomposition, releasing phosphorus-containing species such as diethyl phosphinic acid. These volatile compounds actively intervene in the combustion cycle by scavenging high-energy radicals like hydrogen (H•) and hydroxyl (OH•) radicals, which are crucial for sustaining flames. This interruption of radical chain reactions significantly reduces flame propagation and heat release, enhancing overall fire safety. The formation of an aluminum phosphate residue and a dense aluminum oxide film on the char surface further bolsters this protective action.


The efficacy of ADP is underpinned by its impressive material properties. It is a fine, white powder characterized by a high phosphorus content, typically ranging from 22% to 24%, which directly contributes to its potent flame retardancy. ADP exhibits remarkable thermal stability, with a decomposition temperature exceeding 350°C. This attribute makes it particularly well-suited for engineering plastics that require high processing temperatures, ensuring its integrity and performance during manufacturing. Furthermore, ADP is non-hygroscopic and possesses very low solubility in water and common organic solvents, contributing to its stability and ease of incorporation into various polymer systems. Its good dispersibility ensures uniform distribution within the matrix, leading to consistent flame retardant performance and allowing for good colorability of the final product.


The versatility of Aluminum Diethyl Phosphinate extends across a broad spectrum of applications, making it indispensable in diverse industries. It is widely utilized in various engineering plastics, including polyamides (PA), polyesters (PBT and PET), and thermosetting resins such as epoxy composites and unsaturated polyesters. Its superior performance is also evident in thermoplastic elastomers like TPE-E, SEBS, EVA, and TPU. Specific applications include critical electrical and electronic components such as switches, plugs, and personal computer fans, as well as structural and housing components for consumer electronics like smartphones and washing machines. Additionally, ADP is applied in special cables, melt adhesives, thin-walled electronic materials, and even aircraft parts, where stringent fire safety standards are paramount. Its ability to help materials achieve UL94 V-0 flame retardancy, even at thin sections, makes it a preferred choice for demanding applications. For enhanced performance, ADP can be synergistically combined with other halogen-free additives, such as melamine polyphosphate, to create highly effective fire protection systems.


Beyond its technical merits, Aluminum Diethyl Phosphinate offers significant environmental and health advantages. As a halogen-free solution, it avoids the concerns associated with brominated or chlorinated flame retardants, contributing to a safer and more sustainable product lifecycle. Independent assessments, such as the GreenScreen® Benchmark 3 rating, affirm its favorable environmental and health profile compared to many conventional alternatives, signifying it as a "use but still opportunity for improvement" chemical. While it demonstrates persistence, a property often necessary for its high-temperature application in engineering plastics, its overall hazard profile is considered low.


NINGBO INNO PHARMCHEM CO.,LTD. is dedicated to providing cutting-edge solutions for polymer fire safety. For manufacturers seeking a dependable supplier of high-performance flame retardants, our Aluminum Diethyl Phosphinate offers an optimal balance of flame retardancy, mechanical properties, and environmental responsibility. We strive to provide competitive price and comprehensive technical support to ensure successful integration into your products. To buy or purchase this essential material and explore how it can elevate the fire safety of your applications, interested parties are invited to explore our offerings for a robust and sustainable fire safety solution.

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NINGBO INNO PHARMCHEM CO.,LTD. was established in 2007. It is committed to the R&D, production and sales of raw materials, pharmaceutical intermediates and fine chemicals. We striving to create a high-efficiency and high-quality integrated chemical service platform to better serve domestic and foreign customers.

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2. Own R&D laboratory, pilot platform and large-scale production workshop, which can meet the audit requirements of global customers;

3. We can satisfy customers' perfect transition from small scale lab requirements (gram level) to commercialization requirements (hundred tons level).

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Address: No.163 Ruiqing Rd.,Ningbo 315000 China
Phone: 86-574-87319282
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