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Advanced Thiuram Disulfides: Essential Rubber Accelerators

In the dynamic world of rubber manufacturing, the selection of appropriate accelerators is paramount to achieving optimal product performance, efficiency, and safety. Among the most versatile and effective compounds are thiuram disulfides, specifically N, N'-Diethyl-N, N'-Diphenylthiuram Disulfide, commonly known as Te (EPTD) with CAS No. 41365-24-6, and N, N'-Dimethyl-N, N'-Diphenylthiuram Disulfide, designated as DDTS or MPTD with CAS No. 10591-84-1. These advanced chemical auxiliaries play a critical role in the vulcanization process, dictating the final properties and durability of rubber products across various industries.


N, N'-Diethyl-N, N'-Diphenylthiuram Disulfide (Te EPTD) is a white to light yellow powder renowned for its efficiency as a rubber additive. With a molecular formula of C18H20N2S4 and a molecular weight of 392.61, Te (EPTD) exhibits an initial melting point of 135.0 ºC or higher. Its properties include solubility in common organic solvents like benzene and chloroform, while remaining insoluble in acetone, ethanol, carbon tetrachloride, ethyl acetate, gasoline, and water. This characteristic profile makes it a stable and easily manageable component within rubber formulations. Te (EPTD) acts as a powerful vulcanization accelerator, facilitating the cross-linking of rubber polymers to enhance strength, elasticity, and overall mechanical properties, which are crucial for producing high-quality rubber goods.


Complementing Te (EPTD) is N, N'-Dimethyl-N, N'-Diphenylthiuram Disulfide (DDTS/MPTD). This off-white to gray-white powder, with a molecular formula of C16H16N2S4 and a molecular weight of 364.56, boasts a higher initial melting point of 180.0 ºC or more. DDTS/MPTD shares similar solubility characteristics with Te (EPTD), being soluble in benzene and chloroform and insoluble in water and other common solvents. What truly sets DDTS/MPTD apart is its function as a late-acting accelerator. This property is particularly valuable in improving the processing safety of rubber compounds, allowing for a longer scorch time while still achieving rapid vulcanization. It is frequently utilized as a secondary accelerator in conjunction with compounds like TMTD, TMTM, or zinc dithiocarbamates, contributing to a more controlled and efficient manufacturing process.


The combined application of these thiuram disulfides offers significant advantages. DDTS/MPTD is especially recommended for light-colored and colored rubber products due to its non-polluting and non-discoloring nature. It disperses easily within the rubber matrix, ensuring homogeneity and consistent performance. This makes it ideal for a wide range of applications, including short-time fast vulcanization molded products, impregnated goods, and fabric-coated rubber. The improved processing safety means reduced waste and enhanced productivity, directly impacting overall operational efficiency and cost-effectiveness in rubber production.


The successful integration of these accelerators into manufacturing processes relies on high-quality sourcing and stringent production standards. Leading manufacturers and suppliers prioritize consistent purity and reliability to ensure predictable outcomes in vulcanization. Research and development efforts are continuously focused on optimizing the synthesis and application of these crucial additives, ensuring they meet evolving industry demands for performance and environmental responsibility. When looking to buy these essential rubber additives, partnering with a reputable manufacturer and supplier is key to securing materials that consistently meet specified chemical and physical properties. Enquiries regarding the price and various purchase options are always welcomed, ensuring seamless procurement for your production needs.


In conclusion, Te (EPTD) and DDTS (MPTD) are indispensable components in modern rubber technology. Their unique properties and synergistic effects provide manufacturers with the tools to produce high-performance rubber products with enhanced durability, improved processing characteristics, and superior aesthetic qualities. The continued availability of high-purity thiuram disulfides is vital for the sustained growth and innovation within the global rubber industry.

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