Intermediates

4-Bromo-1,2-dichlorobenzene

  • CAS No.18282-59-2
  • GradeIndustrial / Pharmaceutical
  • Availability● In Stock

High-purity 4-Bromo-1,2-dichlorobenzene (CAS 18282-59-2), a versatile halogenated aromatic intermediate for pharmaceutical and agrochemical synthesis.

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Product Technical Details

Product Overview

4-Bromo-1,2-dichlorobenzene (CAS 18282-59-2) is a highly valuable halogenated aromatic compound widely employed as a key building block in the synthesis of complex organic molecules. With its unique substitution pattern—featuring bromine and two adjacent chlorine atoms on the benzene ring—it offers excellent regioselectivity for cross-coupling reactions such as Suzuki, Stille, and Ullmann-type transformations. This makes it an indispensable intermediate in the development of active pharmaceutical ingredients (APIs), crop protection agents, and specialty materials.

Specifications

Molecular FormulaC6H3BrCl2
Molecular Weight225.90 g/mol
AppearanceColorless to pale yellow liquid or solid
Assay≥98.0%
Water Content≤0.50%
Melting Point24–25 °C (lit.)
Boiling Point237.0 ± 0.0 °C at 760 mmHg
Density1.7 ± 0.1 g/cm³
LogP3.94
Water SolubilityInsoluble

Industrial Applications

As a multifunctional aryl halide, 4-Bromo-1,2-dichlorobenzene serves primarily as a synthetic intermediate in the pharmaceutical and agrochemical industries. Its bromine atom is more reactive than the chlorine substituents under palladium-catalyzed conditions, enabling selective functionalization while preserving the dichloro motif for subsequent modifications. Common applications include:

  • Synthesis of heterocyclic scaffolds for drug discovery programs
  • Preparation of advanced intermediates for antifungal and anti-inflammatory agents
  • Building block in the manufacture of high-performance polymers and liquid crystals
  • Use in research laboratories for method development in C–H activation and halogen exchange chemistry

Stored in a cool, dry, and well-ventilated area with the container tightly sealed, this compound maintains stability under recommended conditions. Standard packaging is 25 kg per drum, with custom options available to meet specific industrial requirements.