Intermediates

L-Glutamic Acid 5-Methyl Ester

  • CAS No.1499-55-4
  • GradeIndustrial / Pharmaceutical
  • Availability● In Stock

High-purity L-Glutamic Acid 5-Methyl Ester (CAS 1499-55-4), ≥98%, widely used as a key chiral intermediate in pharmaceutical and peptide synthesis.

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Product Technical Details

Product Overview

L-Glutamic Acid 5-Methyl Ester (CAS 1499-55-4) is a chemically protected derivative of the naturally occurring nonessential amino acid L-glutamic acid. This compound serves as a versatile building block in organic and medicinal chemistry, particularly valued for its role in solid-phase peptide synthesis and as a precursor in the development of neuroactive pharmaceutical agents. With a molecular formula of C6H11NO4 and a molecular weight of 161.16 g/mol, it maintains the chiral integrity essential for stereospecific syntheses.

Specifications

Molecular FormulaC6H11NO4
Molecular Weight161.16 g/mol
AppearanceWhite powder
Purity≥98%
Chloride Content (Cl)≤0.05%
Loss on Drying≤0.50%
Melting Point182 °C (dec.)
Density1.242 g/cm³
Boiling Point316.1 °C at 760 mmHg
Refractive Index[α]²⁹D = +29° (c = 2, 6 mol/L HCl)

Industrial Applications

As a gamma-esterified glutamate derivative, L-Glutamic Acid 5-Methyl Ester is primarily employed as a synthetic intermediate in the production of complex pharmaceutical active ingredients (APIs), especially those targeting neurological pathways. Its ester functionality allows for selective protection during multi-step syntheses, enabling precise control over reactivity in peptide coupling and side-chain modifications. While L-glutamic acid itself functions as a neurotransmitter in the central nervous system, this methyl ester form is not used directly in therapeutics but rather as a critical tool in R&D and GMP-compliant manufacturing processes.

  • Ideal for chiral pool synthesis and asymmetric transformations
  • Compatible with Fmoc/t-Boc strategies in peptide chemistry
  • Stable under standard handling conditions when stored properly
  • Meets stringent quality requirements for pharmaceutical intermediates

Storage & Handling

Store at 2–8 °C in a tightly sealed container, protected from moisture and light. Keep in a cool, dry environment. Standard industrial hygiene practices should be followed during handling. Packaging is typically 25 kg per drum, with custom options available upon request.